miércoles, 28 de marzo de 2012

IUPAC rules for for naiming carboxilic acids

IUPAC rules for naiming carboxilic acids.

Rule 1: Select as the parent carbon chain that incluides the carbon atom of the carboxyl group.


Rule 2: Name the parent chain by changing the –e ending of the corresponding alkane to –oic acid.


Rule 3: Number the parent chain by assigning the number one to the carboxylic carbon atom, but omit this number from the name.


Rule 4: Determine the identity and location of any substituents  in the usual maner, and append this information to the front of the parent chain name.


Rule 5: If the carbonyl group is bonded to a carbon ring, name the ring and add the words carboxylic acid. The carbon bearing the carboxyl group is always carbon 1.Locate any other ring substituents in the usual name.


Examples:

The root name is based on the longest chain including the carboxylic acid group, therefore suffix= -oic acid.


Hydrocarbon structure is an alkane therefore –ane


The longest continuous chain is C4 therefore root =but





Butanoic acid

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